Search results for "Thiol group"

showing 4 items of 4 documents

Selection of probiotic strains and improving the survival and functionality of an academic strain, Bifidobacterium bifidum, by changing the redox pot…

2012

The aim of this work was to select rationally a probiotic strain by setting up a screening method as well as study and understand the impact of the redox potential (Eh) and gas bubbling on the survival of Bifidobacterium bifidum in a fermented dairy product. In a first time, we have developed selection techniques of probiotic bacteria on the criteria of viability / vitality (flow cytometry analysis) and on the criteria of functionality (antioxidant). We were able to select strains of industrial interest as well as an academic strain, Bifidobacterium bifidum.Secondly, we have studied effect of modifying redox potential by gas bubbling on the survival of B. bifidum in a fermented dairy produc…

[SDV.SA] Life Sciences [q-bio]/Agricultural sciences[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionGroupements thiolsPouvoir antioxydantPotentiel redox[SDV.AEN] Life Sciences [q-bio]/Food and Nutrition[CHIM.OTHE] Chemical Sciences/Other[ CHIM.OTHE ] Chemical Sciences/OtherScreeningBactéries probiotiquesFermented dairy productsBifidobacterium bifidumAntioxidantRedox potentialProduits laitiers fermentés[ SDV.SA ] Life Sciences [q-bio]/Agricultural sciencesThiol groupsProbiotic strains
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Highly selective and sensitive chromo-fluorogenic detection of the Tetryl explosive using functional silica nanoparticles

2011

Silica nanoparticles containing polyamines and thiol groups have been used as probes for the selective detection of Tetryl. © 2011 The Royal Society of Chemistry.

PolyamineINGENIERIA DE LA CONSTRUCCIONUnclassified drugNanoparticlePhotochemistryColorimetry (chemical method)Nitrobenzenechemistry.chemical_compoundNanoparticleQUIMICA ORGANICAChemical structureSilicon dioxidePolyaminesMaterials ChemistryChemical analysischemistry.chemical_classificationAniline CompoundsChemistryMetals and Alloysrespiratory systemTetrylSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsThiolColorimetryDyeExplosive materialSilicon dioxideChemical structureArticleCatalysisThiol groupBinding site246 trinitrophenylmethylnitramineExplosive AgentsExplosiveReaction analysisQUIMICA ANALITICASulfhydryl CompoundsNitrobenzenesSensorFluorescent DyesFluorescent dyeQUIMICA INORGANICAGeneral ChemistrySilane derivativeCombinatorial chemistryChromogenic substrateCeramics and CompositesNanoparticlesChemical Communications
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An efficient probe for sensing different concentration ranges of glutathione based on AIE-active Schiff base nanoaggregates with distinct reaction me…

2018

Abstract A novel tetraphenylethene-diketopyrrolopyrrole Schiff base (TPE-DPP) was synthesized by one-pot protocol. Based on thiol group and acid-base property of glutathione, nanoaggregates of TPE-DPP for sensitive and selective detection of diff ;erent concentration ranges of glutathione by two distinct reaction mechanisms was reported. It showed a turn-on mode of fluorescence signals towards low concentration of GSH by hydrolysis of TPE-DPP, but a ratiometric mode of fluorescence signal was elicited towards high concentration of GSH by addition reaction of thiol with TPE-DPP. What’s more, the probe was successfully utilized for monitoring GSH in living cells.

Reaction mechanismanimal structures02 engineering and technology010402 general chemistryPhotochemistry01 natural sciencesThiol groupchemistry.chemical_compoundHydrolysisMaterials ChemistryElectrical and Electronic EngineeringInstrumentationchemistry.chemical_classificationHigh concentrationAddition reactionSchiff baseMetals and AlloysGlutathione021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryThiol0210 nano-technologySensors and Actuators B: Chemical
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Coupling of Contact Sensitizers to Thiol Groups is a Key Event for the Activation of Monocytes and Monocyte-Derived Dendritic Cells

2003

Strong contact sensitizers are able to induce distinct signal transduction mechanisms in antigen-presenting cells by coupling to cell proteins. The predominant target structures of haptens are thought to be thiol and amino groups in cysteine and lysine residues. We studied whether coupling of small reactive chemicals to thiol or amino groups might be responsible for the activation of monocytes and mature monocyte-derived dendritic cells. Human peripheral blood mononuclear cells were stimulated in vitro with subtoxic concentrations of the strong haptens 5-chloro-2-methylisothiazolinone plus 2-methylisothiazolinone and 2, 4, 6-trinitrochlorobenzene, the thiol-reactive reagents N-hydroxymaleim…

MAP Kinase Signaling SystemCD14SuccinimidesPicryl ChlorideDermatologyAcetatesPeripheral blood mononuclear cellBiochemistryamino groupsAntioxidantsMonocytesMaleimideschemistry.chemical_compoundAnti-Infective AgentsmedicineHumansCysteineSulfhydryl CompoundsPhosphorylationAntigen-presenting cellMolecular Biologythiol groupsChemistryMonocyteLysineSulfhydryl ReagentsTyrosine phosphorylationDendritic cellDendritic CellsCell BiologyThiazolesmedicine.anatomical_structureBiochemistryEthylmaleimidehaptenTyrosineSignal transductionsignal transductionCysteineInterleukin-1Journal of Investigative Dermatology
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